Acrylonitrile Production from Different Feedstocks: technological prospecting
DOI:
https://doi.org/10.9771/cp.v15i3.46123Keywords:
Acrylonitrile, Prospecting, Production.Abstract
The great worldwide demand for acrylonitrile, combined with the increasing need for more sustainable and competitive processes has motivated the constant improvement in the process, as well as the search for more sustainable raw feedstocks for it. Thus, a scientifical and technological prospecting was carried out on this topic, to better understand the current technological scenario, especially with regarding to the use of the main raw materials mentioned in the literature. For that, the articles were researched on the Science Direct, and for the patents, the Espacenet was employed, using the indexing code C07B and keywords referring to acrylonitrile. It was found that most articles and patents are focused on improving catalysts and reaction conditions, with propane and propene as the most addressed raw materials. Few publications have addressed the production of acrylonitrile from renewable inputs, such as glycerol, indicating that this kind of process is still poorly consolidated.
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BAGHERI, S.; JULKAPLI, N. M. Mo3VOx catalyst in biomass conversion: A review in structural evolution and reaction pathways, International Journal of Hydrogen Energy, [s.l.], v. 42, p. 2.116-2.126, 2017. DOI: https://doi.org/10.1016/j.ijhydene.2016.09.173.
BELL, A. T. Insights into the mechanism and kinetics of propene oxidation and ammoxidation over bismuth molybdate catalysts derived from experiments and theory, Journal of Catalysis, [s.l.], v. xx, p. xxx, 2021. DOI: https://doi.org/10.1016/j.jcat.2021.05.009.
BRAZDIL, J. F. Acrylonitrile. In: KROSCHWITZ, J. I.; HOWE-GRANT, M. (ed.). Kirk-Othmer – Encyclopedia of Chemical Technology. 4th ed. New York: John Wiley, 1991. v. 1, p. 352-369.
CESPI, D. et al. Life Cycle Assessment comparison of two ways for acrylonitrile production: the SOHIO process and an alternative route using propane. Journal of Cleaner Production, [s.l.], v. 69, p. 17-25, 2014. DOI: https://doi.org/10.1016/j.jclepro.2014.01.057.
ESPACENET. Portal. [2021]. Disponível em: https://worldwide.espacenet.com/?locale=en_EP. Acesso em: 4 nov. 2021.
GRASSELLI, R. K.; TRIFIRÒ, F. Acrylonitrile from Biomass: Still Far from Being a Sustainable Process. Top Catal, [s.l.], v. 59, p. 1.651-1.658, 2016. DOI: https://doi.org/10.1007/s11244-016-0679-7.
GUERRERO-PÉREZ, M. O.; BAÑARES, M. A. New Reaction: Conversion of Glycerol into Acrylonitrile. ChemSusChem, [s.l.], v. 1, p. 511-513, 2008. DOI: https://doi.org/10.1002/cssc.200800023.
GUERRERO-PÉREZ, M. O.; MCCUE, A.; ANDERSON, J. A. Rapid scan ftir reveals propane (am)oxidation mechanisms over vanadium based catalysts. Journal of Catalysis, [s.l.], v. 390, p. 72-80, 2020. DOI: 10.1016/J.Jcat.2020.07.031.
IEA – INTERNATIONAL ENERGY AGENCY. Oil 2021 – Analysis and forecast to 2026. [S.l.]: International Report, 2021.
ITC. Acrylonitrile (292610). [2022]. Disponível em: https://www.trademap.org/Country_SelProduct _TS.aspx?nvpm=1%7C%7C%7C%7C%7C292610%7C%7C%7C6%7C1%7C1%7C1%7C2%7C1%7C2%7C1%7C%7C1. Acesso em: 2 fev. 2022.
KARP, E. M. et al. Renewable acrylonitrile production. Science, [s.l.], v. 358, p. 1.307-1.310, 2017. DOI: 10.1126/science.aan1059.
LE NÔTRE, J. et al. Biobased synthesis of acrylonitrile from glutamic acid. Green Chem., [s.l.], v. 13, p. 807-809, 2011. DOI: https://doi.org/10.1039/C0GC00805B.
LICHT, R. B.; VOGT, D.; BELL, A. T. The mechanism and kinetics of propene ammoxidation over α-bismuth molybdate, Journal of Catalysis, [s.l.], v. 339, p. 228-241, 2016. DOI: https://doi.org/10.1016/j.jcat.2016.04.012.
LIEBIG, C. et al. Glycerol conversion to acrylonitrile by consecutive dehydration over WO3/TiO2 and ammoxidation over Sb-(Fe,V)-O. Applied Catalysis B: Environmental, [s.l.], v. 132, p. 170-182, 2013. DOI: https://doi.org/10.1016/j.apcatb.2012.11.035.
MACK, D. et al. Synthesis of Acrylonitrile from Renewable Lactic Acid. Chem Sus Chem, [s.l.], v. xx, p. xx, 2019. DOI: 10.1002/cssc.201802914.
REZAIE, Fatemeh; PIROUZFAR, Vahid; ALIHOSSEINI, Afshar. Technical and economic analysis of acrylonitrile production from polypropylene. Thermal Science and Engineering Progress, [s.l.], v. 16, 2020. DOI: https://doi.org/10.1016/j.tsep.2019.100463.
SCHAECHTER, M. Encyclopedia of Microbiology. 3. ed. Nova York: Academic Press, 2009.
SCIENCE DIRECT. Journals & Books. [2021]. Disponível em: https://www.sciencedirect.com/. Acesso em: 2 nov. 2021.
SHELDON, R. A.; SANDERS, J. P. M. Toward concise metrics for the production of chemicals from renewable biomass, Catalysis Today, [s.l.], v. 239, p. 3-6, 2015. DOI: 0.1016/j.cattod.2014.03.032.
TERRY, L. Acrylonitrile Market Slips Out of BP's Control. Chemical Week, [s.l.], p. 54, 25 Nov. 1998.
YU, B. et al. Conceptual design, optimization, and carbon emission analysis for the acrylonitrile/acetonitrile/water separation processes. Journal of the Taiwan Institute of Chemical Engineers, [s.l.], v. 122, p. 32-39, 2021. DOI: https://doi.org/10.1016/j.jtice.2021.04.044.
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