Technological Prospection of Catalysts Employed in Transeterification and Esterification Reactions
DOI:
https://doi.org/10.9771/cp.v12i4.28812Keywords:
Catalyst, Transesterification, Esterification.Abstract
The development of new materials has been increasing over the decades, among which catalysts figure prominently playing an important role in industrial processes when it acts in reactions such as transesterification and esterification for the production of various compounds, such as biofuels. In this work a prospective technological survey of catalysts used in transesterification and esterification reactions was performed. Patent and article searching was performed on different databases using the keywords catalyst AND transesterification AND esterification. This issue has attracted attention in industry and academia as noted in Scopus with the number of publications of 719 documents, with China and India being the leading countries, and the number of patents filled of 216 according to Patent Inspiration, with United States and Japan having relevant positions. Brazil has a growing interest in this scenario through the development and improvement of catalysts.
Downloads
References
ABBASZAADEH, A.; GHOBADIAN, B.; OMIDKHAH, M. R.; NAJ, G. Current biodiesel production technologies: A comparative review. Energy Conversion and Management, v. 63, p. 138–148, 2012.
ALESSIO, C.; RIBEIRO, J. S.; CELANTE, D.; BRONDANI, L.; CASTILHO, F. Kinetics of methyl esters production with dimethyl carbonate over niobium phosphate. Energy Conversion and Management, v. 151, p. 670-680, 2017.
ARANSIONLA, E. F.; OJUMU, T. V.; OYEKOLA, O. O.; MADZIMBAMUTO, T. F.; IKHU-OMOREGBE, D.I.O. A review of current technology for biodiesel production: State of the art. Biomass & Bioenergy, v. 61, p. 276-297, 2014.
BANKOVIĆ–ILIĆ, I. B.; MILADINOVIĆ, M.R.; STAMENKOVIĆ, O. S. ; VELJKOVIĆ, V. B. Application of nano CaO-based catalysts in biodiesel synthesis. Renewable and Sustainable Energy Reviews, v. 72, p. 746-760, 2017.
BRITO, Y. C.; FERREIRA, D. A. C.; FRAGOSO, D. M. A.; MENDES, P. R.; OLIVEIRA, C. M. J.; MENEGHETTI, M. R.; MENEGHETTI, S. M. P. Simultaneous conversion of triacylglycerides and fatty acids into fatty acid methyl esters using organometallic tin(IV) compounds as catalysts. Applied Catalysis A: General, v. 443, p. 202-206, 2012.
EPO - European Patent Office. Disponível em: https://worldwide.espacenet.com/advancedSearch?locale=en_EP. Acesso em: 21 jul. 2018.
EVANGELISTA, J. P. C.; GONDIM, A. D.; SOUZA, L. D.; ARAUJO, A. A. Aluminasupported potassium compounds as heterogeneous catalysts for biodiesel production: Areview. Renewable and Sustainable Energy Reviews, v. 59, p. 887-894, 2016.
FERREIRA, D. A. C.; MENEGHETTI, M. R.; MENEGHETTI, S. M. P. M.; WOLF, C. R. Methanolysis of soybean oil in the presence of tin(IV) complexes. Applied Catalysis A: General, v. 317, p. 58–61, 2007.
HOSSAIN, M. A.; IQBAL, M. A. M.; JULKAPLI, N. M.; KONG, P. S.; CHING, J. J.; LEE, H. V. Development of catalyst complexes for upgrading biomass into ester-based biolubricants for automotive applications: a review. Royal Society of Chemical Advances, v. 8, p. 5.559-5.577, 2018.
INPI - Instituto Nacional da Propriedade Intelectual. Disponível em: https://gru.inpi.gov.br/pePI/jsp/patentes/PatenteSearchAvancado.jsp. Acesso em: 21 jul. 2018.
JAMIL, F.; AL-HAJ, L.; AL-MUHTASEB, A. H.; AL-HINAI, M. A.; BAAWAIN, M.; RASHID, U.; AHMAD, M. N. M. Current scenario of catalysts for biodiesel production: a critical review. Review in Chemical Engineering, v. 34, p. 267-297, 2018.
LEE, H.; KIM, S. J.; AHN, B. S.; LEE, W. K.; KIM, H. S. Role of sulfonic acids in the
Sn-catalyzed transesterification of dimethyl carbonate with phenol. Catalysis Today, v. 87,
p. 139-144, 2003.
LENARDÃO, E. J.; FREITAG, R. A.; DABDOUB, M. J.; BATISTA, A. C. F.; SILVEIRA, C. C. Green chemistry- The 12 principles of green chemistry and it insertion in the teac and research activities. Química Nova, v. 26, p. 123-129, 2003.
NUNES, R. S.; ALTINO, F. M.; MENEGHETTI, M. R.; MENEGHETTI, S. M. P. New mechanistic approaches for fatty acid methyl ester production reaction in the presence of Sn(IV) catalysts. Catalysis Today, v. 289, p. 121-126, 2017.
PEDRO, K. C. N. R.; PARREIRA, J. M.; CORREIA, I. N.; HENRIQUES, C. A.; LANGONE, M. A. P. Enzymatic biodiesel synthesis from acid oil using a lipase mixture. Química Nova, v. 41, p. 284-291, 2018.
PI - Patent Inspiration. Disponível em: https://app.patentinspiration.com/#report/ac76C7f12E0F/filter. Acesso em: 21 jul. 2018.
PIROUZMAND, M.; ANAKHATOON, M. M.; GHASEMI, Z. One-step biodiesel production from waste cooking oils over metal incorporated MCM-41; positive effect of template. Fuel, v. 216, p. 296-300, 2018.
QUITAIN, A. T.; SUMIGAWA, Y.; MISSION, E. G.; SASAKI, M.; ASSABUMRUNGRAT, S.; KIDA, T. G Graphene Oxide and Microwave Synergism for Efficient Esterification of Fatty Acids. Energy & Fuel, v. 32, p. 3.599-3.607, 2018.
RAIA, R. Z.; DA SILVA, L. S.; MARCUCCI, S. M. P.; ARROYO, P. A. Biodiesel production from Jatropha curcas L. oil by simultaneous esterification and transesterification using sulphated zircônia. Catalysis Today, v. 289, p. 105-114, 2017.
SALIMON, J.; SALIH, N.; YOUSIF, E. Industrial development and applications of plant oils and their biobased oleochemicals. Arabian Journal of Chemistry, v. 5, p. 135-145, 2012.
SCIENCE DIRECT. Disponível em: https://www.sciencedirect.com/search/advanced. Acesso em: 21 jul. 2018.
SCOPUS. Disponível em: https://www-scopus.ez9.periodicos.capes.gov.br/search/form.uri?display=advanced&origin=searchbasic&txGid=d614293cd7194d9c5032935634b02e2f. Acesso em: 21 jul. 2018.
SERRA, T. M.; MENDONÇA, D. R.; SILVA, J. P.V.; MENEGHETTI, M. R.; MENEGHETTI, S. M. P. Comparison of soybean oil and castor oil methanolysis in the presence of tin(IV) complexes. Fuel, v. 90, p. 2.203-2.206, 2011.
SHARMA, S.; SAXENA, V.; BARANWAL, A.; CHANDRA, P.; PANDEY, L. M. Engineered nanoporous materials mediated heterogneous catalyst and their implications in biodiesel production. Materials Science for Energy Technologies, v. 1, p. 11-21, 2018.
SHULI, Y.; STEVEN, S.; SIMON, N. K. Y. ZnO nanoparticle catalysts for use in transesterification and esterification reactions and method of making. Titular: University Wayve State, 2012.
SIDDARAMAIAH, M. B. Synthesis and characterization of polyurethane/ polybutyl
methacrylate interpenetrating polymer networks. Journal of Materials Science, v. 39, p.
615-4.623, 2004.
SILVA, J. P. V.; BRITO, Y.C.; FRAGOSO, D. M. A.; MENDES, P. R.; BARBOSA, A. S. L.; BORTOLUZZI, J. H.; MENEGHETTI, M. R.; MENEGHETTI, S. M. P. Influence of different alkyl and carboxylate substituents on Sn(IV)
organometallic catalysts during fatty acid methyl ester production. Catalysis
Communications v. 58, p. 204–208, 2015.
SUAREZ, P. A. Z.; MENEGHETTI, S. M. P.; MENEGHETTI, M. R.; WOLF, C. R.;
Transformação de triacilglicerídeos em combustíveis, materiais poliméricos e insumos
químicos: algumas aplicações da catálise na oleoquímica. Química Nova, v. 30, n.
, p. 667-676, 2007.
WEB OF SCIENCE. Disponível em: http://apps-webofknowledge.ez9.periodicos.capes.gov.br/WOS_AdvancedSearch_input.do?SID=5BGrLes5NHToCeKYOX9&product=WOS&search_mode=AdvancedSearch. Acesso em: 21 jul. 2018.
WIPO – World Intellectual Property Organization. Disponível em: https://patentscope.wipo.int/search/pt/structuredSearch.jsf. Acesso em: 21 jul. 2018.
XIE, W.; YANG, X.; FAN, M. Novel solid base catalyst for biodiesel production:
Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine. Renewable Energy, v. 80, p. 230-237, 2015.
YADAY, M.; UPADHYAY, S.; SHARMA, Y. C. Process optimization, kinetics of production Jatropha curcus methyl ester, and its utilization in single cylinder diesel engine. Energy Conversion and Management, v. 160, p. 364-374, 2018.
YAN, K.; JARVIS, C.; GU, G.; YAN, Y. Production and catalytic transformation of levulinic acid: A platform for speciality chemicals and fuels. Renewable and Sustainable Energy Reviews, v. 51, p. 986-997, 2015.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2019 Cadernos de Prospecção
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
O autor declara que: - Todos os autores foram nomeados. - Está submetendo o manuscrito com o consentimento dos outros autores. - Caso o trabalho submetido tiver sido contratado por algum empregador, tem o consentimento do referido empregador. - Os autores estão cientes de que é condição de publicação que os manuscritos submetidos a esta revista não tenham sido publicados anteriormente e não sejam submetidos ou publicados simultaneamente em outro periódico sem prévia autorização do Conselho Editorial. - Os autores concordam que o seu artigo ou parte dele possa ser distribuído e/ou reproduzido por qualquer forma, incluindo traduções, desde que sejam citados de modo completo esta revista e os autores do manuscrito. - Revista Cadernos de Prospecção está licenciado com uma Licença Creative Commons Attribution 4.0. Esta licença permite que outros remixem, adaptem e criem a partir do seu trabalho para fins não comerciais, e embora os novos trabalhos tenham de lhe atribuir o devido crédito e não possam ser usados para fins comerciais, os usuários não têm de licenciar esses trabalhos derivados sob os mesmos termos.
Este obra está licenciado com uma Licença Creative Commons Atribuição 4.0 Internacional.
